Kinetics of hydrocarbon generation from the marine Ordovician Goldwyer Formation, Canning Basin, Western Australia

Pyrolysis and bulk kinetic studies were used to investigate the hydrocarbon generation potential and source rock facies variability of the marine organic-rich rocks from the Middle Ordovician (Darriwilian) Goldwyer Formation in the Canning Basin, Western Australia. Rock Eval pyrolysis results for the analysed immature to mid-mature calcareous mudstones imply that the upper Goldwyer Sequence I samples contain oil-prone Type I kerogen, while the lower Goldwyer Sequence III samples comprise on average Type II/III oil- and gas-prone kerogen. This is supported by the pyrolysis gas chromatography (Py-GC) results that show the presence of homogenous organofacies in the Goldwyer Sequence I that comprise aliphatic molecular signatures, possibly attributed to the selective preservation of the lipid fraction derived from Gloeocapsomorpha prisca (G. prisca). The heterogeneous organofacies of the Goldwyer Sequence III contains aromatic moieties that are present in similar abundance as the aliphatic compounds. The calcareous claystones of the Goldwyer Sequence I have the capacity to generate paraffinic oil with low wax contents, whereas those of the Goldwyer Sequence III have generative potential for paraffinic-naphthenic-aromatic (P-N-A) low wax oils and gas and condensate.

The temperature for hydrocarbon generation for the Type I kerogen, assuming a constant geological heating rate of 3oC/Ma, is estimated to occur over a narrow interval between 145oC and 170oC for the Goldwyer Sequence I samples. Generation from the Type II/III kerogen occurs from 100°C to 160°C in the Goldwyer Sequence III samples which are significantly thermally less stable than observed for the Goldwyer Sequence I samples. The kinetics results for both sequences were used in standard thermal and burial history plots to evaluate their transformation ratio and hydrocarbon generative potential. This provided a basin-specific kinetic input for burial history modelling and a better constraint for kerogen transformation and hydrocarbon generation on the Broome Platform.

Citation: Lukman M. Johnson, Reza Rezaee, Gregory C. Smith, Nicolaj Mahlstedt, Dianne S. Edwards, Ali Kadkhodaie, Hongyan Yu,; Kinetics of hydrocarbon generation from the marine Ordovician Goldwyer Formation, Canning Basin, Western Australia, International Journal of Coal Geology, Volume 232, 2020, 103623, ISSN 0166-5162, https://doi.org/10.1016/j.coal.2020.103623.